Main Villains are villains who have a major role in something.
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- Madame Gasket
- Maestro Forte
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- Maleficent
- Margaret White
- Marina Del Ray
- Mary Lou Maloney
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- Maxim Horvath
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- Mechagodzilla (MonsterVerse)
- Megatron (Generation One)
- Mikey Miller
- Miss Finch
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- Mitch and Tiff
- Moff Gideon
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- Morag (The Loud House)
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- Sam Harper
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- Scorm
- Scoutmaster Lumpus
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- Sebastian Shaw
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- Shang Tsung (Mortal Kombat 1995 film)
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- Shere Khan (2018)
- Sir John Talbot
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- Skullcrawlers
- Smithy
- Snowy (mlpd)
- Spinosaurus (Jurassic Park 3)
- Springtrap (Tony Crynight 1 and 2 Movies)
- Storm King
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